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Utilisation d’un agent gonflant sans impact sur l’appauvrissement de l’ozone pour développer et produire en masse une mousse rigide de polyuréthane destinée à un transporteur de GNL.

Development of mass production type rigid polyurethane foam for LNG carrier using ozone depletion free blowing agent.

Auteurs : LEE Y., BAEK K. H., CHOE K., et al.

Type d'article : Article

Résumé

Nowadays the price of natural gas has become higher and the efficiency of propulsion system of liquefied natural gas (LNG) carriers has improved. Due to these trends, required boil-off rate (BOR) for LNG carrier has been lowered from 0.15%/day to 0.12%/day for conventional LNG carriers with sizes between 125,000 m3 and 170,000 m3. This requirement of BOR can be satisfied by using a rigid polyurethane foam (PUF) blown by 1,1-dichloro-1-fluoroethane (HCFC-141b) as an insulator. However, ozone depletion potential (ODP) of HCFC-141b requires alternative blowing agents with zero ODP such as hydroflurocarbons (HFCs) because of tougher environmental regulations. This paper introduces use of HFCs and additives to enhance properties of rigid PUFs under a mass production environment. Among the additives, perfluoroalkane (PFA) reduces thermal conductivity down to 12% and increases compressive strength up to 15% of a rigid PUF prepared in a laboratory scale. Based on this result, a mass production type rigid PUF is manufactured and is evaluated for BOR, mechanical strengths over operation temperature range,
and thermal shock stability for LNG carriers. The BOR of the manufactured rigid PUF is below 0.12%/day, which satisfies the recent BOR specification for LNG carriers. The other required properties are also met the specifications for a conventional LNG carrier. Consequently, it is expected that the results in this paper will bring low BOR (<0.12%/day) LNG carries with rigid PUFs using ODP free blowing agents and contribute environmental protection through saving energy and preserving the ozone layer in the stratosphere.

Détails

  • Titre original : Development of mass production type rigid polyurethane foam for LNG carrier using ozone depletion free blowing agent.
  • Identifiant de la fiche : 30020879
  • Langues : Anglais
  • Source : Cryogenics - vol. 80
  • Date d'édition : 09/2016
  • DOI : http://dx.doi.org/10.1016/j.cryogenics.2016.09.002

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