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Vitesse du son et coefficients du viriel pour le mélange binaire 2,3,3,3-tétrafluoropropène (R1234yf) + 1,1,1,2-tétrafluoroéthane (R134a) à l’état gazeux.

Gaseous speed of sound and virial coefficients for 2,3,3,3-tetrafluoropropene (R1234yf) + 1,1,1,2-tetrafluoroethane (R134a) binary mixture.

Auteurs : PENG X., XU L., LI J., YANG Z., DUAN Y.

Type d'article : Article de la RIF

Résumé

The binary mixture 2,3,3,3-tetrafluoropropene (R1234yf) + 1,1,1,2-tetrafluoroethane (R134a) is commercially interesting and is widely studied in thermodynamics properties, but except for gaseous speed of sound. In this work, we modified the experimental procedure of the cylindrical fixed-path acoustic resonance method for the sound speed measurement of mixtures. Then we obtained the first two sets of gaseous sound speed data at the molar fraction of about (0.207/0.793) and (0.580/0.420) with a combined relative expanded uncertainty (k = 2) of 0.03%. The accurate molar fractions along each isotherm line were determined by extrapolating the experimental data with the absolute expanded uncertainty (k = 2) of 0.003. The interaction virial coefficients were derived from the experimental sound speed data and were used to establish a hard-core square-well molecular potential model. A previous virial coefficient correlation was modified to predict the virial coefficients for mixtures. The experimental results and model calculations agree well with each other, confirming the correctness of the experimental method. The data could provide references to test and develop the mixing model.

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Pages : p. 314-323

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Détails

  • Titre original : Gaseous speed of sound and virial coefficients for 2,3,3,3-tetrafluoropropene (R1234yf) + 1,1,1,2-tetrafluoroethane (R134a) binary mixture.
  • Identifiant de la fiche : 30032007
  • Langues : Anglais
  • Sujet : Technologie
  • Source : International Journal of Refrigeration - Revue Internationale du Froid - vol. 154
  • Date d'édition : 10/2023
  • DOI : http://dx.doi.org/10.1016/j.ijrefrig.2023.07.002

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