Étude des propriétés thermiques d'un matériau à changement de phase grâce à un système optique à calorimètre par balayage différentiel.
Study on thermal properties of phase-change material by an optical DSC system.
Auteurs : WANG H. Y., LU S. S.
Type d'article : Article
Résumé
An optical differential scanning calorimeter (DSC) system was used in studying the thermal properties of phase-change material (PCM). In this study, several typical PCMs were studied in terms of their thermal properties by the optical DSC system. These PCMs are sodium sulfate (Na2SO4·10H2O), paraffin, n-octadecane, and the paraffin/n-octadecane composites at different mass ratios. The thermal properties and micro-structure change of these PCMs were mainly investigated. The results showed that for Na2SO4·10H2O, paraffin and n-octadecane, the measured phase-change temperatures and enthalpies showed no large relative deviation (<5%) from the theoretic values. A high measurement accuracy of the optical DSC system was obtained and inferred from the experimental results. For the paraffin/n-octadecane composites, the measured phase-change temperatures appeared to be lower than that of paraffin, and could be adjusted from 24.2°C to 49.6°C by changing the mass fractions of n-octadecane. The lowest eutectic temperature was obtained at the mass fraction 40% of n-octadecane. The measured phase-change enthalpies, however, showed no large variation between 186.4 J/g (paraffin) and 230.5 J/g (n-octadecane). And according to the micro-photos before and after phase change, n-octadecane existed as crystal particles which disappeared at increasing temperatures and was finally combined with the paraffin matrix.
Détails
- Titre original : Study on thermal properties of phase-change material by an optical DSC system.
- Identifiant de la fiche : 30008380
- Langues : Anglais
- Source : Applied Thermal Engineering - vol. 60 - n. 1-2
- Date d'édition : 10/2013
- DOI : http://dx.doi.org/10.1016/j.applthermaleng.2013.06.055
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