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Effect of three-body interactions between dissimilar molecules on the phase behaviour of binary mixtures: the transition from vapour-liquid equilibria to type III behaviour.

Author(s) : SADUS R. J.

Type of article: Article

Summary

The authors demonstrate that three-body interactions can induce a transition from vapour-liquid equilibria to type IIIb behaviour in a model fluid. The transition is observed despite the fact that three-body interactions make a relatively small contribution to the overall energy of the fluid. However, any inference for real fluids must be tempered by the limitations of the intermolecular potentials used.

Details

  • Original title: Effect of three-body interactions between dissimilar molecules on the phase behaviour of binary mixtures: the transition from vapour-liquid equilibria to type III behaviour.
  • Record ID : 1999-2112
  • Languages: English
  • Source: Ind. eng. Chem. Res. - vol. 37 - n. 8
  • Publication date: 1998/08
  • Document available for consultation in the library of the IIR headquarters only.

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