IIR document

Non-equilibrium sorption performances for composite sorbents of chlorides-ammonia working pairs for refrigeration.

Author(s) : ZHOU Z. S., WANG L. W., JIANG L., et al.

Type of article: Article, IJR article

Summary

The sorption/ desorption characteristics under the non-equilibrium conditions are extremely important for the refrigeration. The experimental test unit is set up, and the p-T-x curves of different working pairs are tested under the non-equilibrium working conditions. The results show that non-equilibrium sorption/ desorption processes are related with dual variables rather than a single variable. Then we tested the isobaric sorption/ desorption processes of chlorides. Results show that the hysteresis phenomena are related with the desorption enthalpy. Sorption/ desorption dynamic models are studied. For sorption process the model is in accord with D-A equation, but for the desorption process both D-A equation and Spinner model should be considered. The Arrhenius equation is used to fit the relation between reaction heat and desorption hysteresis. The results show that the non-equilibrium equations fit the refrigeration performance well, whereas the theoretical equilibrium curves have big error.

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Pages: 60-68

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Details

  • Original title: Non-equilibrium sorption performances for composite sorbents of chlorides-ammonia working pairs for refrigeration.
  • Record ID : 30017258
  • Languages: English
  • Source: International Journal of Refrigeration - Revue Internationale du Froid - vol. 65
  • Publication date: 2016/05

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