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Enhancement of the extended corresponding states techniques for thermodynamic modelling. I. Pure fluids.

Author(s) : PIAZZA L., SCALABRIN G., MARCHI P., et al.

Type of article: Article, IJR article

Summary

This work, limited to pure fluids' modelling, has two main goals. The first one is to discuss in a rigorous way the modelling background of the conventional extended corresponding states (ECS) methods proposed in the literature. A critical review is in the meantime developed allowing to point out the limits of the methods. The second goal is to propose a practicable and plain solution for the use of ECS as the basic framework to develop a fundamental equation of state for a target fluid in a totally correlative mode. For this purpose the conventional analytical procedure was left out and an optimization procedure, based on a general function approximator, was applied. The model capability to accurately represent several thermodynamic surfaces of a number of haloalkanes is verified assuming data generated from the corresponding equations of state. The achieved results show that the method is robust and straightforward, while the obtained prediction accuracies for the thermodynamic functions are competitive with those of the available conventional equations of state. See also this Bulletin, reference 2006-2233.

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Pages: 1182-1194

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Details

  • Original title: Enhancement of the extended corresponding states techniques for thermodynamic modelling. I. Pure fluids.
  • Record ID : 2006-2234
  • Languages: English
  • Source: International Journal of Refrigeration - Revue Internationale du Froid - vol. 29 - n. 7
  • Publication date: 2006/11

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