Superconductivity in lanthanum-nickel boron-nitride.

Summary

The authors report superconductivity at 12-13 K in a new quaternary intermetallic system, lanthanum nickel boron-nitride. They have determined the formula and crystal structure of superconducting lanthanum(3)-nickel(2)-boron(2)-nitrogen(3) (and also of a related non-superconducting phase lanthanum-nickel-boron-nitrogen). The crystal structure consists of three rock-salt-type lanthanum-nitrogen layers alternating with tetrahedral nickel(2)-boron(2) layers, an arrangement considerably more two-dimensional than is found for the superconducting boro-carbides. These discoveries strongly suggest that a large number of unusual superconducting intermetallic phases are yet to be found, based on materials more complex than have previously been considered as candidates for superconductivity.

Details

  • Original title: Superconductivity in lanthanum-nickel boron-nitride.
  • Record ID : 1996-1393
  • Languages: English
  • Source: Nature - vol. 372 - n. 6503
  • Publication date: 1994/11/17
  • Document available for consultation in the library of the IIR headquarters only.

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