ShareCryochemistry: esterification in frozen dioxane solution.
Author(s) : VAJDA T.
Type of article: Article
Summary
The freezing effect on esterification of acids of different polarity has been investigated in dioxane solution and compared with the results obtained in liquid phase. The freezing of the dioxane solutions resulted in a significant increase of yield of methyl benzoate, however, ester formation of the other acids became nearly similar in liquid and frozen conditions. The role of freezing and polarity of the acids in the ester yield is discussed. A further purpose of the present investigations was to demonstrate the possibility of esterification in frozen conditions.
Details
- Original title: Cryochemistry: esterification in frozen dioxane solution.
- Record ID : 1999-3912
- Languages: English
- Source: Cryo-Letters - vol. 19 - n. 6
- Publication date: 1998/11
- Document available for consultation in the library of the IIR headquarters only.
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