Global warming potential (GWP) of HFC refrigerants

Using the latest updated data from UNEP’s RTOC 2022 report, we have compiled the 100-year GWP and 20-year GWP values of hydrofluorocarbon-based (HFC) refrigerants. Our table includes single component HFCs as well as blends that include at least one HFC in their composition.

Global warming potential (GWP) definition

 

The Global warming potential (GWP) is the metric most commonly used to indicate the climate impact potential of a refrigerant emission. [1] According to UNEP, GWP can be defined as a measure of the relative global warming effects of different gases (in this case, refrigerants). It assigns a value to the amount of heat trapped by a certain mass of a refrigerant relative to the amount of heat trapped by the same mass of carbon dioxide over a specific period of time.[2] Carbon dioxide was chosen by the Intergovernmental Panel on Climate Change (IPCC) as the reference gas and its GWP is equal to 1.

 

Consistent with the Kigali Amendment, the IIR uses GWP values for the 100-year timeframe in its publications.[3] The 100-year GWP is more commonly used in scientific articles, standards, and regulations, which is helpful for an efficient discussion of the climate impact.[1] Some experts advocate the use of GWP values with shorter integration time horizons, particularly in the case of HFCs which often have relatively short lifetimes. Indeed, a 20-year time horizon is more relevant when discussing climate change during the next few decades, where it may also be better in differentiating between substances with shorter lifetimes.[1]

 

100-year and 20-year GWP values of HFC-based refrigerants

 

The table below presents 100-year GWP and 20-year GWP values for HFC refrigerants. We listed blends that include at least one HFC in their composition. This means that our table also include HFC/HFO blends or HFC/hydrocarbons blends.

The values were extracted from UNEP’s RTOC 2022 report, in which GWP values have been updated according to the World Meteorological Organization (WMO, 2022). In previous reports, namely UNEP’s RTOC 2018 report and UNEP’s TEAP 2021 report, GWP values were sourced from WMO 2019 and the Intergovernmental Panel on Climate Change (IPCC) sixth assessment report, 2021 (AR6).

 

 

Refrigerant designation Type Blend composition Safety Class GWP 100 years GWP 20 years
R125 HFC Single-component   A1 3 820 6 790
R134a HFC Single-component   A1 1 470 4 060
R143a HFC Single-component   A2L 5 900 7 900
R152a HFC Single-component   A2 153 550
R23 HFC Single-component   A1 14 700 12 400
R227ea HFC Single-component   A1 3 580 5 830
R236fa HFC Single-component   A1 9 120 7 820
R245fa HFC Single-component   B1 966 3 190
R32 HFC Single-component   A2L 749 2 620
R41 HFC Single-component     137 492
R404A blend R-125/143a/134a A1 4 808 7 258
R407A blend R-32/125/134a A1 2 266 4 864
R407B blend R-32/125/134a A1 3 043 5 827
R407C blend R-32/125/134a A1 1 892 4 411
R407D blend R-32/125/134a A1 1 714 4 254
R407E blend R-32/125/134a A1 1 642 4 110
R407F blend R-32/125/134a A1 1 959 4 447
R407G blend R-32/125/134a A1 1 511 4 092
R407H blend R-32/125/134a A1 1 588 4 002
R407I blend R-32/125/134a A1 1 529 4 011
R410A blend R-32/125 A1 2 285 4 705
R410B blend R-32/125 A1 2 438 4 914
R413A blend R-218/134a/600a A2 2 149 4 196
R417A blend R-125/134a/600 A1 2 515 5 194
R417B blend R-125/134a/600 A1 3 287 6 107
R417C blend R-125/134a/600 A1 1 903 4 523
R419A blend R-125/134a/E170 A2 3 221 6 000
R419B blend R-125/134a/E170 A2 2 558 5 242
R421A blend R-125/134a A1 2 833 5 643
R421B blend R-125/134a A1 3 468 6 381
R422A blend R-125/134a/600a A1 3 420 6 245
R422B blend R-125/134a/600a A1 2 718 5 440
R422C blend R-125/134a/600a A1 3 353 6 177
R422D blend R-125/134a/600a A1 2 950 5 699
R422E blend R-125/134a/600a A1 2 793 5 534
R423A blend R134a/227ea A1 2 472 4 901
R424A blend R-125/134a/600a/600/601a A1 2 620 5 337
R425A blend R-32/134a/227ea A1 1 590 4 006
R426A blend R-125/134a/600/601a A1 1 562 4 122
R427A blend R-32/125/143a/134a A1 2 392 4 911
R427B blend R-32/125/143a/134a A1 2 765 5 192
R427C blend R-32/125/143a/134a A1 2 320 4 767
R428A blend R-125/143a/290/600a A1 4 141 6 842
R429A blend R-E170/152a/600a A3 16 56
R430A blend R-152a/600a A3 117 418
R431A blend R-290/152a A3 45 160
R434A blend R-125/143a/134a/600a A1 3711 6 363
R435A blend R-E170/152a A3 31 111
R437A blend R-125/134a/600/601 A1 1 899 4 511
R438A blend R-32/125/134a/600/601a A1 2 432 5 073
R439A blend R-32/125/600a A2 2 170 4 501
R440A blend R-290/134a/152a A2 173 603
R442A blend R-32/125/134a/152a/227ea A1 2 041 4 443
R444A blend R-32/152a/1234ze(E) A2L 98 346
R444B blend R-32/1234ze(E)/152a A2L 327 1 145
R445A blend R-744/134a/1234ze(E) A2L 133 370
R446A blend R-32/1234ze(E)/600 A2L 510 1 783
R447A blend R-32/125/1234ze( E) A2L 643 2021
R447B blend R-32/125/1234ze(E) A2L 815 2 326
R448A blend R-32/125/1234yf/134a /1234ze(E) A1 1 497 3 300
R448B blend R-32/125/1234yf/134a/1234ze€ A1 1 415 3 235
R449A blend R-32/125/1234yf/134a A1 1 504 3 358
R449B blend R-32/125/1234yf/134a A1 1 519 3 419
R449C blend R-32/125/1234yf/134a A1 1 340 3 060
R450A blend R-1234ze(E)/134a A1 618 1 708
R451A blend R-1234yf/134a A2L 151 416
R451B blend R-1234yf/134a A2L 166 456
R452A blend R-1234yf/32/125 A1 2 336 4 295
R452B blend R-32/125/1234yf A2L 769 2 231
R452C blend R-32/125/1234yf A1 2 424 4 470
R453A blend R-32/125/134a/227ea/600/601a A1 1 884 4 358
R454A blend R-32/1234yf A2L 263 918
R454B blend R-32/1234yf A2L 516 1 806
R454C blend R-32/1234yf A2L 162 565
R455A blend R-744/32/1234yf A2L 162 565
R456A blend R-32/134a/1234ze(E) A1 707 1 987
R457A blend R-32/1234yf/152a A2L 154 539
R457B blend R-32/1234yf/152a A2L 278 973
R457C blend R-32/1234yf/152a A2L 79 278
R458A blend R-32/125/134a/227ea/236fa A1 1 747 4 136
R459A blend R-32/1234yf/1234ze(E) A2L 510 1 782
R459B blend R-32/1234yf/1234ze(E) A2L 158 552
R460A blend R-32/125/134a/1234ze( E) A1 2 282 4 415
R460B blend R-32/125/134a/1234ze(E) A1 1 459 3 244
R460C blend R-32/125/134a/1234ze(E) A1 791 2 105
R461A blend R-125/143a/134a/227ea/600a A1 3 045 5 720
R462A blend R-32/125/143a/134a/600 A2 2 437 5 032
R463A blend R-744/32/125/1234yf/134a A1 1 622 3 549
R464A blend R-32/125/1234ze(E)/227ea A1 1 449 2 893
R465A blend R-32/290/1234yf A2 158 552
R466A blend R-32/125/13I1 A1 807 2 065
R467A blend R-32/125/134a/600a A1 1 420 3 855
R468A blend R-1132a/32/1234yf A2L 162 565
R468B blend R-1132a/32/1234yf A2L 98 342
R468C blend R-1132a/32/1234yf A2L 315 1102
R469A blend R-744/HFC- 32/HFC-125 A2L 1 485 3 059
R470A blend R-744/32/HFC-125/HFC-134a/HFO-1234ze(E)/HFC-227ea A1 1 064 2 197
R470B blend R-744/HFC-32/HFC-125/HFC-134a/HFO-1234ze(E)/HFC-227ea A1 821 1 615
R471A blend R-1234ze(E)/227ea/1336mzz( E) A1 159 271
R472A blend R-744/HFC-32/HFC-134a A1 370 1 086
R472B blend R-744/32/134a A1 546 1 562
R473A blend R-1132a/23/744/125 A1 1 853 1 920
R503 blend R-23/13 A1 15 658 12 400
R507A blend R-125/143a A1 4 860 7 345
R508A blend R-23/116 A1 13 419 10 350
R508B blend R-23/116 A1 13 566 10 586
R512A blend R-134a/152a A2 219 726
R513A blend R-1234yf/134a A1 647 1 788
R513B blend R-1234yf/134a A1 611 1 686
R515B blend R-1234ze( E)/227ea A1 320 523

 

 

Useful links for further information

 

UNEP/ASHRAE. Update on New Refrigerants Designations and Safety Classifications April 2023.
https://iifiir.org/en/fridoc/update-on-new-refrigerants-designations-and-safety-classifications-2023-147209
UNEP. (2023). Refrigeration, Air Conditioning and Heat Pumps Technical Options Committee (RTOC) 2022 Assessment Report (Montreal Protocol on Substances That Deplete the Ozone Layer.). https://iifiir.org/en/fridoc/montreal-protocol-on-substances-that-deplete-the-ozone-layer-2022-146932

 

 

Acknowledgements

 

This document was prepared by Monique Baha (IIR Scientific and Technical Information Department) and proofread by Maud Grasmenil, under the supervision of Jean-Luc Dupont (Head of the Scientific and Technical Information Department).

 

 

References

[1] UNEP. (2023). Refrigeration, Air Conditioning and Heat Pumps Technical Options Committee (RTOC) 2022 Assessment Report (Montreal Protocol on Substances That Deplete the Ozone Layer.). https://ozone.unep.org/system/files/documents/RTOC-assessment%20-report-2022.pdf

[2] UNEP. (2016). Global Warming Potential (GWP) of Refrigerants: Why are Particular Values Used? https://wedocs.unep.org/xmlui/handle/20.500.11822/28246

[3] Domanski, P., & Motta, S. Y. (2022). Low-GWP Refrigerants: Status and Outlook. 48th Informatory Note on Refrigeration Technologies. IIF-IIR. https://doi.org/10.18462/iif.NItec48.06.2022